Cornellab
@CornellaLab
Followers
11K
Following
4K
Media
65
Statuses
1K
Synthesis focused. Catalysis driven. At Max-Planck-Institut für Kohlenforschung
Mülheim an der Ruhr
Joined April 2017
Yes, it is a bismuthinidene. Yes, it is stable. Yes, it is a triplet. Yes, it is non-magnetic.
25
110
777
Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2
13
116
493
Catalytic synthesis of phenols with N2O. An enormous effort spearheaded by @FranckF1476 !Congrats to all the authors involved.
7
65
467
Bi-catalyzed radical catalysis with redox-active esters. Congrats to everyone involved! .
6
44
375
A new story on Bismuth Redox Catalysis: this time, triflate and nonaflate as nucleophiles. Great work from @uri_planas and Vytautas!
4
46
340
Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. @J_A_C_S with @ShengyangN & @DavideSpinnato2
4
36
339
The fluorination of boronic esters through bismuth redox catalysis is now out in Science.
36
47
321
Deaminative Chlorination of Aminoheterocycles: bringing the best of the Vilsmeier disconnection to late-stage. 5- and 6-member rings. >20 heterocyclic scaffolds. Sneak peak of what @ChemRxiv @ClementGhiazza, Teresa and Alejandro!
5
38
268
Single electron oxidative addition at Bismuth unlocks radical cross-coupling catalysis in C-N couplings. Work led by @mato_mauro. Great job from all involved!
1
38
264
Reporting in @J_A_C_S: low-valent Bi redox catalysis via elementary organometallic steps: catalytic hydrodefluorination. Excellent work by Yue (@YPYuePang) Markus (@MrIrieman), Nils and Felix!
3
44
256
Honored to be part of these outstanding group. Thanks to all the co-workers at the @CornellaLab @maxplanckpress for their dedication and passion during these years! 👍🏽.
10
14
234
Catalytic activation of N2O at a Bi-redox platform made possible by Yue. Together with @MrIrieman and Nils! @J_A_C_S
7
26
215
Activation of N-H and O-H bonds at Bi. Led by @sdyangxiu. A great story together with the @mpicec_press. Congrats to all people involved! @ChemRxiv
0
35
208
2
26
169
The deaminative chlorination protocol developed by @ClementGhiazza, Teresa and Alejandro👇🏽has found a home: Including more examples, alternative solvents and expanding halogenation to fluorination.
Deaminative Chlorination of Aminoheterocycles: bringing the best of the Vilsmeier disconnection to late-stage. 5- and 6-member rings. >20 heterocyclic scaffolds. Sneak peak of what @ChemRxiv @ClementGhiazza, Teresa and Alejandro!
0
22
166
Pyrylium tetrafluoroborate (Pyry-BF4) now available on @SigmaAldrich @MilliporeSigma. For examples of its power as NH2 activator:
1
17
147
Aryl-S(VI)-Fluorides: strange compounds with rich chemistry. @M_Magre and @ShengyangN have organized the precedents and looked at their chemistry. Out now in @angew_chem . Congrats!
0
11
128
0
13
125
Functionalization of aminoheterocycles via C-N bond cleavage? Pyry-BF4 will do the trick. Check the great work from Daniel and Yaya:
4
33
120
Our recent developments on pyrylium reagents:.- Pyry-BF4: Sulfonyl Fluoride Synthesis from Sulfonamides.- ScPyry-OTf: Radical Borylation of Anilines .
0
14
115
Bismuth, often overlooked in the periodic table, breaks into redox catalysis. Thanks to @chitnislab for the comments!!👍🏽
1
6
103
Great to see this collaborative work on the bismuthinidene finally out. Congrats to this amazing team of people!.
Plus out in First Release from @CornellaLab it’s 1-coordinate triplet bismuth!
1
4
104
OMG🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥🔥.
BREAKING NEWS: .The 2021 #NobelPrize in Chemistry has been awarded to Benjamin List and David W.C. MacMillan “for the development of asymmetric organocatalysis.”
0
1
100
. and the countdown is over! Bringing catalysis to a forgotten beast. Congratulations to Lukas, Sigrid, Pascal and Richard!!
1
19
91
0
8
82
Another piece of the puzzle: Ni-norbornene as catalyst in low-temperature Kumada cross-coupling. Good job Sigrid, Lukas and Nils! @Orgmet_ACS
0
11
81
Learning more about high-valent Bi(V)-F cationic compounds, thanks to the amazing work of Jenni, Marc and Nils! 👍.
0
0
72
Interested in starting your independent career?.2022-Tenure-track-faculty-position | Max-Planck-Institut für Kohlenforschung @maxplanckpress
0
27
71
@FranckF1476 revisited the C(sp3)-O-C(sp3) bond formation at high-valent Ni centers and found interesting structures and reactivity. A truly collaborative work at the Mülheim Chemistry Campus with @MrIrieman and Edward @mpicec_press! @J_A_C_S
0
12
67
Lukas and Sigrid receiving the traditional beer shower to celebrate their great work being published in @J_A_C_S!!
3
2
68
After 1 year in the post, first article out! Congrats Matt & Tim! Starting a new trend in the group!
5
7
62
- Review on pyrylium chemistry by Yue and @DMAO_92: @thiemechemistry . - News and Views on Baudoin @NatureCatalysis article: by @uri_planas
2
7
60
Thanks @ribas_xavi ! Extremely honored to receive this prize. This goes to all the group members for all their work and contributions!.
Marcial Moreno-Mañas 2019 award to:.- Josep Cornellà Costa (Max-Planck-Institut für Kohlenforschung). Quin crack! Many congrats @CornellaLab !!!.
11
1
60
Late-stage C-H functionalization anyone? any substituent? selectively? with functional group tolerance? check the latest from the @ritter_lab in @nature
1
9
56
OPEN ACCESS ALERT. Glad to share that both of our articles of this year 2019 are now open access in @J_A_C_S !! @maxplanckpress
1
10
57
Stop by to see what @JenniferKuziola has been up to!.
Really excited to present my work on bismuth chemistry at #ACSFall2022 conference. So if you are interested in fluorobismuthonium cations❄️ developed in @CornellaLab , stop by my poster 2463 at today’s poster session!
0
3
57
Thrilled to see our work with Pyry-BF4 highlighted in Synfacts! @thiemechemistry !! @DIYDuan @DMAO_92 👍🏽
2
7
54
Congrats to our very own @uri_planas for the more than deserved recognition from the @RSEQUIMICA with the Young Investigator Award-Postdoc!! Super proud!!👍🔥🔥.
2
2
57
Our postdoc Uri just got a Humboldt Fellowship!!! Congratulations, great achievement!! @AvHStiftung #celebration
1
4
49
One of the best coworkers one can have! Wishing you all the best in this new and exciting adventure! Enjoy the ride! Watch out for some awesome stuff from the Planas lab!.
Last month I left Germany and said farewell to @CornellaLab and the MPI. 3.5y of postdoc surrounded by fantastic people and a brilliant mentor, exploring Bi catalysis. I will miss you all!. Looking forward to new challenges as #newPI at @Chemistry_QMUL @QMUL!. Let's go!🔥🔥
1
1
46
Late but still valid: congratulations to Feng Wang for being named one of the finalist of the #ReaxysPhDPrize. Well done!!👍
0
6
37
#fakenews we did not win the cup, but we stole it just for a quick picture! We will come back stronger next year for the KoFo Cup!! 💪🏾💪🏾 well done people!!!!! 5th place!!!
0
0
36
Good luck Hanna in this new adventure! It was a pleasure to work with you. Looking forward to chemistry from the Moon Lab!.
Plus, I am excited to share that I will be joining the Chemistry faculty of DGIST as an Assistant Professor next month! I am very grateful to my advisors, Alex Radosevich and Pep Cornella (@CornellaLab), for their mentorship and immense support.
2
1
34
And our paper is out in the Early View in @angew_chem. Check it out!
Thorpe-Ingold Effect in Branch-Selective Alkylation of Unactivated Aryl Fluorides (Cornella)
0
4
31
Congratulations to our very own @FranckF1476 for winning the european championship of landsailing in Terschelling (NED)!! Amazing!!🥇🏆
2
1
26
Coming back to my office, after the department lecture at the MPI-Kofo. This group is da best!!👍🏽👍🏽💪🏾💪🏾
1
0
26
Thinking on doing redox catalysis with this guy. Maybe removing 1 electron. ?
0
0
25
Check out this incredible work from former postdoc colleague Prof. Chao Li!! Redox-esters in Cu-catalyzed reductive cascade coupling in total synthesis!
0
7
25
Congrats Bill!!!🔥🔥🔥🔥🔥👇🏽👇🏽.
The @ETH_en Board appointed new professors, among them Bill Morandi #LOC @ETH_DCHAB @morandilab as Full Professor of Synthetic Organic Chemistry. Karl-Heinz Altmann #IPW, Full Professor of Pharmaceutical Biology, will retire at the end of July 2022.
0
0
25
More good news!! Congratulations!!.
ICIQ is on a roll 🍾 #congratulations to @AntonioMEchavar (@Echavarren_Lab) for his 🆕 (2nd!) ERC Advanced Grant! 2.5 M€ to develop new types of catalysts inspired by natural cyclase enzymes ➖🔜➰ Read more: #ERCAdG @ERC_Research
1
0
25
The reductive Liebeskind-Srogl reaction developed by Yuanhong and Jose has been one of the most read articles in @J_A_C_S !! Congrats!!
0
5
23
Our article on the SNAr of heteroaromatic amines via Pyry-BF4 is now in the Early View. This is a taste of what we have been able to do.
0
1
23
Beat the heat! beer pouring to beat the (unusual) 37 deg in Mülheim. Congrats Daniel and Yaya for the @angew_chem on the Pyry-BF4!
3
0
23
Having trouble in retaining your C(sp3)-M in the cross-coupling of aryl electrophiles? here is an overview of methods available! @thiemechemistry
0
4
23
Make sure to stop by at the posters from our laboratory at #omcos20 @OMCOSBoard!! Feng Wang will explain you all the adventures with Bi!👍🏽
0
3
22
Check @uri_planas explaining the development of Bismuth redox catalysis in detail! 💪🏾🔥.
This week we're joined by Dr. @uri_planas (Marie Curie Postdoc @CornellaLab) on a new Research Spotlight episode all about bismuth catalysis!. @ScienceMagazine 2020, 367, 313-317. @J_A_C_S 2020, 142, 11382-11387. #BiREDOX #RealTimeChem #ChemTwitter.
0
1
23
0
1
21
Today we say goodbye to Yaya Duan 😢 The first postdoc in our group!! Best of luck in this new adventure at @ICIQchem in @MartinLab_ICIQ 👍🏽
1
0
20
WE pledge to oppose racism and hate through active allyship, continuous unlearning, learning, and listening. Join us by nominating 5 others to do the same. #BlackLivesMatter I nominate @FleischerLab @Tsogoeva_Group @TeichertLab @OlallaLab.
0
0
20
Our paper on Pyry-BF4 reagent to functionalize Aminoheterocycles has been one of the most accessed of July in @angew_chem !! Congratulations Daniel, @DIYDuan, Yuanhong, Feng and Matt!
1
2
19
Our Reductive Liebeskind-Srogl protocol has been highlighted by Synfacts @thiemechemistry and @OPRD_ACS!! Congrats Yuanhong and Jose!
2
1
17
We fought until the end! Next year we will come back stronger!!! Go KOFO CUP team!! Good luck to @ListLaboratory!!!
1
0
16
Congrats to our PhD student @LNattmann for 1st poster prize!! Awesome!! 👍🏽.
Congratulations to Felix Raps (@christof_sparr), Franziska Reuss (@HeretschPhilipp), Valentin Geier (@FleischerLab) and Lukas Natmann (@CornellaLab) receiving the poster and talk prizes at #HtI2019 #hochschuletrifftindustrie! @merck_de
1
0
16
Our expert on Ni catalysis Lukas Nattmann (@LNattmann) will be giving a talk at #ISySyCat on Wed at 6:15 pm on his developments in Low-valent Ni complexes! Don’t miss it! 👍🏽👍🏽🔥🔥.
0
0
15
Amazing lecture and extremely useful work. 👍🏽.
Opening up the next session of the ESOC, from Denmark (@AarhusUni) - Prof. Troels Skrydstrup (@TroelsTs) with his Low Pressure Carbonylation Reactions #esocwien
1
1
14
Our research group has been highlighted in the lokal newspaper Mülheimer Woche!! 👍🏿
0
2
15
Remember the day you guys decided to tackle this!! Great to see it accomplished!! Congrats to all the team!👍🏽.
🎄SMALL ENOUGH TO FIT IN A STOCKING🎁: Total syntheses of Herqulines from our group ( and @JohnWoodGroup group (! Behind the scenes account of our "simply strained" effort here at Open Flask:
1
0
15
Today we say good bye to our excellent technician Pascal!!! Good luck in Lanxess!!!!
0
0
12
Reading: One-Pot Absolute Stereochemical Identification of Alcohols via Guanidinium Sulfate Crystallization | Organic Letters
1
3
12
Amazing collaborative effort between Kofo and @mpicec_press !! Congrats to all contributors!!.
0
2
11
