The Ito Group
@sgitolab
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198
Organic Chemistry / School of Chemistry, Chemical Engineering and Biotechnology / Nanyang Technological University
Singapore
Joined April 2017
Delighted to announce that our new paper has just been published in Nature Communications! Congratulations to Weifan, Fiona, and Yosuke for their amazing teamwork. We never stop extending the pi-surface of azabuckybowls.
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Long time no tweet. Our latest paper on a new cationic buckyball as a mitochondrial probe is now online in Angew Chem Int Ed! Collaboration with Prof. Xing.
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Just Accepted in @angew_chem: A new cyclophane molecule bearing the largest polycyclic heteroarene. Congrats, Xinjiang!!.
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Our first @NatureSynthesis paper on the synthesis of azahexabenzocoronenium by a formal [3 + 3] cycloaddition strategy is out now, in collaboration with Profs. S. Kawai and A. S. Foster. Congrats to all my group members involved in this project!.
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Azahomocorannulene molecules just came out in @angew_chem. Congrats to Yosuke and Kotaro. Great collaboration with @TapaviczaEnrico. RADLESS is amazing. Synthesis and Properties of Azahomocorannulenyl Cations and Radicals
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Our new paper on the second example of fused azacorannulene dimers is now out in @CCSChemistry!.Great work by Weifan and Fiona in collaboration with Prof. Webster.
Delighted to announce that our new paper has just been published in Nature Communications! Congratulations to Weifan, Fiona, and Yosuke for their amazing teamwork. We never stop extending the pi-surface of azabuckybowls.
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Our new paper about the synthesis of π-extended heteropines, which exhibit high mobility in organic field-effect transistors, is now online in @angew_chem. Great collaboration with Prof. Yasuda group of Kyushu University in Japan.
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1,3-Dipolar Cycloaddition of Azomethine Ylides and Imidoyl Halides for Synthesis of π-Extended Imidazolium Salts. Our new paper is now published in Organic Chemistry Frontiers!.
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Our latest paper on "multiazacorannulene" is published online and will be included in the first issue of Precision Chemistry, a new journal of @AmerChemSociety . Great work by Kimihiro, Kotaro, and Ayaka and good collaboration with Dr. He and Dr. Miyajima.
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A fully funded Ph.D scholarship is available for admission in January 2025. If you are interested in joining our research group, please check the admission requirement on the website and contact us.
We are looking for a Ph.D candidate interested in joining our group at Nanyang Technological University in Singapore. We have an opening for a fully funded scholarship for the August 2024 or January 2025 intake. Please contact us if you are interested.
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Pagoda[4]arene and i-Pagoda[4]arene (Han and Chen) J. Am. Chem. Soc.
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Had a great post #ISNA20 meeting at Boston with @RJGilliard and @cromeronieto. Can't wait to visit to MIT tomorrow.
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Our azomethine ylides react with nitriles to form π-extended imidazoles. Check out our latest work published in Organic Letters. Congrats for Qiang-Qiang, Kotaro, and Cherie.
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Synthesis of a Carbon Nanocone by Cascade Annulation (Würthner) J. Am. Chem. Soc.
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On-Surface Synthesis and Characterization of a Cycloarene: C108 Graphene Ring (Ebeling and Gottfried) J. Am. Chem. Soc.
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Oxidative Electrocyclization of Diradicaloids: C–C Bonds for Free or How to Use Biradical Character for p-Extension (Feofanov and Amsharov) Org. Lett.
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Another paper of ours has just been accepted in a top journal. Coming soon 👀.
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We are looking for a Ph.D candidate interested in joining our group at Nanyang Technological University in Singapore. We have an opening for a fully funded scholarship for the August 2024 or January 2025 intake. Please contact us if you are interested.
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Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation (Murata) Or. Lett.
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Resolving Quinoid Structure in Poly(para-phenylene) Chains (Wang) J. Am. Chem. Soc.
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Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts (Segawa and Itami) J. Am. Chem. Soc.
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Synthesis of Circumpyrene by Alkyne Benzannulation of Brominated Dibenzo[hi,st]ovalene (Müllen and Narita) J. Am. Chem. Soc.
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Exploration of the Solid-State Sorption Properties of Shape-Persistent Macrocyclic Nanocarbons as Bulk Materials and Small Aggregates (Schaub and Jasti) J. Am. Chem. Soc.
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Congratulations to Ayaka! // Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution (Tsurusaki and Kamikawa) J. Am. Chem. Soc.
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Benzo-Fused Periacenes or Double Helicenes? Different Cyclodehydrogenation Pathways on Surface and in Solution (Narita, Müllen, and Chi) J. Am. Chem. Soc.
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Hybrid of Corannulene and Azacorannulene: Synthesis of a Highly Curved Nitrogen‐Containing Buckybowl - Ito - - Angewandte Chemie International Edition - Wiley Online Library
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Helically Chiral Aromatics: The Synthesis of Helicenes by [2+2+2] Cycloisomerization of p-Electron Systems (Stará and Starý) Acc. Chem. Res.
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π-Extended C2-Symmetric Double NBN-Heterohelicenes with Exceptional Luminescent Properties (Wu and Zhang) Org. Lett.
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On-Surface Synthesis of Unsaturated Carbon Nanostructures with Regularly Fused Pentagon–Heptagon Pairs (Narita, Fasel, and Müllen) J. Am. Chem. Soc.
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Functionalization of Azapentabenzocorannulenes via Five‐fold C‐H Borylation and Cross‐Coupling Arylation: Application to Columnar Liquid Crystalline Materials (Ito and Nozaki) Chem. Eur. J.
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Phenanthrylene Butadiynylene Macrocycles to S-Heterocycloarenes
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Enhancement of Antiaromatic Character via Additional Benzoannulation into Dibenzo[a,f]pentalene: Syntheses and Properties of Benzo[a]naphtho[2,1-f]pentalene and Dinaphtho[2,1-a,f]pentalene (Konishi, Nakano, and Yasuda) J. Am. Chem. Soc.
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Extended Bis(anthraoxa)quinodimethanes with Nine and Ten Consecutively Fused Six-Membered Rings: Neutral Diradicaloids and Charged Diradical Dianions/Dications (Chi) J. Am. Chem. Soc.
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[Review] Structurally Constrained Boron-, Nitrogen-, Silicon-, and Phosphorus-Centered Polycyclic p-Conjugated Systems (Yamaguchi) Chem. Rev.
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Diazuleno‐s‐indacene Diradicaloids: Syntheses, Properties, and Local (anti)Aromaticity Shift from Neutral to Dicationic State (Chi) Angew. Chem. Int. Ed.
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Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons (Tilley) J. Am. Chem. Soc.
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Open-Shell Effects on Optoelectronic Properties: Antiambipolar Charge Transport and Anti-Kasha Doublet Emission from a N-Substituted Bisphenalenyl (Chen) J. Am. Chem. Soc.
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Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry (Kubota and Ito) Nature Commun.
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Synthesis, Structures, and Properties of Neutral and Radical Cationic S,C,C-Bridged Triphenylamines (Kato) Org. Lett.
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Lemniscular [16]Cycloparaphenylene: A Radially Conjugated Figure-Eight Aromatic Molecule (Casado and Stępień) J. Am. Chem. Soc.
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Bowl-shaped Carbon Nanobelts Showing Size-dependent Properties and Selective Encapsulation of C70 (Wu) J. Am. Chem. Soc.
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Synthesis of a Porphyrin(2.1.2.1) Nanobelt and Its Ability To Bind Fullerene (Kuzuhara and Yamada) Org. Lett.
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Nanoribbons with Nonalternant Topology from Fusion of Polyazulene: Carbon Allotropes beyond Graphene (Ebeling, Hilt, Hieringer, and Gottfried) J. Am. Chem. Soc.
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Stable Olympicenyl Radicals and Their p-Dimers (Sun) J. Am. Chem. Soc.
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A Tetraazapentacene–Pyrene Belt: Toward Synthesis of N-Doped Zigzag Carbon Nanobelts (Miao) Org. Lett.
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Sydnone-Based Approach to Heterohelicenes through 1,3-Dipolar-Cycloadditions (Audisio) J. Am. Chem. Soc.
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Studying natural Buckyballs and Buckybowls in fossil materials (Schrader) Angew. Chem. Int. Ed.
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Linear [3]Spirobifluorenylene: An S-Shaped Molecular Geometry of p-Oligophenyls (Amaya) J. Am. Chem. Soc.
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Fluorous Corannulenes: Ab initio Predictions and the Synthesis of sym‐Pentafluorocorannulene (Baltridge and Siegel) Angew. Chem. Int. Ed.
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Synthesis of Cycloiptycenes from Carbon Nanobelt (Segawa and Itami) Chem. Sci.
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@Scott61144 Thanks, Larry. We will present this reaction with some behind story in the coming ISNA-20!.
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Finite phenine nanotubes with periodic vacancy defects (Isobe) Science 2019, 363, 151.
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Tiara[5]arenes: Synthesis, Solid‐State Conformational Studies, Host‐Guest Properties and Application as Nonporous Adaptive Crystals. (Zuilhof and Sue) Angew. Chem. Int. Ed.
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Placing Metal in the Bowl: Does Rim Alkylation Matter? (Rogachev and Petrukhina) Organometallics
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[Review] Bowls, Hoops, and Saddles: Synthetic Approaches to Curved Aromatic Molecules (Stępień) Angew. Chem. Int. Ed.
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Azoniadibenzo[a,j]phenalenide: A Polycyclic Zwitterion with Singlet Biradical Character (Shimizu and Shintani) Angew. Chem. Int. Ed.
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Folding of Fluorinated Oligoarylenes into Non-alternant PAHs with Various Topological Shapes (Akhmetov and Amsharov) Org. Chem. Front.
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Intramolecular (directed) electrophilic C–H borylation (Ingleson) Chem. Soc. Rev.
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Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction (Shintani and Nozaki) Chem. Commun.
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Tetra‐Aza‐Pentacenes by means of a One‐Pot Friedländer Synthesis (Thompson) Chem. Eur. J.
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Formation of a Large Confined Spherical Space with a Small Aperture Using Flexible Hexasubstituted Sumanene (Sakurai)
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Dehydrative π-extension to nanographenes with zig-zag edges (Amsharov) Nature Commun.
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Holding of Planar Chirality of Pillar[5]arene by Kinetic Trapping Using Host-Guest Interactions with Achiral Guest Solvents (Nagata, Suginome, and Ogoshi) Chem. Commun.
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Polycyclic aromatic hydrocarbon diradical with pH-responsive magnetic properties (Zhao) Chem. Sci.
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Bowls, Hoops, and Saddles: Synthetic Approaches to Curved Aromatic Molecules (Stępień) Angew. Chem. Int. Ed.
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@TapaviczaEnrico @angew_chem Thanks for your great contribution. Looking forward to our next opportunity for collaboration in the future!.
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Helical Ullazine‐Quinoxaline‐Based Polycyclic Aromatic Hydrocarbons (Bunz, Feng, Berger) Chem. Eur. J.
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@DumeleLab @J_A_C_S Thanks! This azomethine ylide is really amazing. Looking forward to seeing your results.
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